Tetrahedron Letters p. 2101 - 2104 (1991)
Update date:2022-07-29
Topics:
Marshall, James A.
Welmaker, Gregory S.
γ-Silyloxy allylstannanes can be prepared directly from α-hydroxy allylstannanes by treatment with TBSOTf and (i-Pr)2NEt in CH2Cl2.The attendant 1,3-isomerization proceeds by an anti pathway as shown by comparison of the absolute configuration of reactant
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Doi:10.1021/jo202241b
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