Controlling benzylic functionality and stereochemistry: 1. Synthesis of the secopseudopterosin aglycone

DOI: 10.1016/S0040-4039(00)71242-1

Source and publish data:

Tetrahedron Letters p. 2083 - 2086 (1991)

Update date:2022-07-30

Topics:

Authors:

McCombie, Stuart W.

Cox, Brian

Lin, Sue-Ing

Ganguly, Ashit K.

McPhail, Andrew T.

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Article abstract of DOI:10.1016/S0040-4039(00)71242-1

Directed, homogeneous hydrogenation of 1-(1-hydroxymethylethyl)-5-methoxy-3,4-dihydronaphthalene (7), followed by protection and selective benzylic oxidation gave the 1-oxo-(4R*, 11R*) compound (13). After addition of MeCeCl₂, the natural C-1 s

Full text of DOI:10.1016/S0040-4039(00)71242-1

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