Tetrahedron Letters p. 8367 - 8370 (1996)
Update date:2022-08-03
Topics:
Griesbeck, Axel G.
Hundertmark, Thomas
Steinwascher, Joerg
1,2-Azidohydroperoxides are accessible from alkenes when irradiated in the presence of azide anions, oxygen and an appropriate sensitizer. The results of substrate/sensitizer variations indicate a reaction initiated by electron transfer to give the sensitizer radical anion and azidyl radicals. The latter efficiently add to alkenes producing carbon radicals which are trapped by molecular oxygen.
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