Angewandte Chemie - International Edition p. 11257 - 11260 (2011)
Update date:2022-08-06
Topics:
Chatterjee, Indranil
Froehlich, Roland
Studer, Armido
Click! Formal [3+2] cycloadditions of 2-nitrosopyridine with various allylstannanes give 4-stannyl-substituted isoxazolidines. The use of [Cu(MeCN)4]PF6, in combination with a Walphos ligand, leads to excellent enantioselectivies and high yields. With cis-2- alkenylstannanes as nucleophiles, 3-alkyl-4-stannyl-substituted isoxazolidines are formed with excellent diastereo- and enantioselectivities. Copyright
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