VIBRATIONAL SPECTRA AND STRUCTURE OF SULFONIUM NITROIMIDES

Article abstract of DOI:10.1007/BF00961030

Vibrational spectroscopy and x-ray structure analysis have been used to investigate three new types of sulfonium nitroimides: N-nitrosulfylimides, N-nitrosulfoximides, and N,N'-dinitrosulfodiimides.Structural parameters have been determined for the molecules (CH3)2S⁺-N^--NO2, (CH3)2S⁺(O)N^-NO2, and (CH3)2S⁺(N^-NO2)2.