ENANTIOSELECTIVE METAL COMPLEX CATALYSIS. 6. RHODIUM CATALYSTS FOR ASYMMETRIC HYDROSILYLATION BASED ON CHIRAL PHOSPHITES

DOI: 10.1007/BF00961341

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 871 - 876 (1991)

Update date:2022-08-03

Topics:

Authors:

Zhorov, E. Yu.

Gavrilov, K. N.

Pavlov, V. A.

Teleshev, A. T.

Gorshkova, L. S.

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00961341

A study has been made of the asymmetric hydrosilylation of acetophenone by diphenylsilane under the influence of rhodium complexes with chiral phosphites.The enantioselective nature of the reaction depends on the phosphite structure, the acetophenone/rhodium and ligand/rhodium ratios, and the temperature.The maximum optical yield (24percent) is attained on the complex 2/(S,S)-2-ethoxy-4,5-dicarbisopropoxy-1,3,2-dioxaphospholane.

Full text of DOI:10.1007/BF00961341

Products guided by the article

Product name:diphenylbornyl phosphite

Cas No:135607-88-4

R&D Labs maybe for 135607-88-4

Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
Tianjin SPHINX SCIENTIFIC LAB.

Contact:+86-022-66211289

Address:Tianda high-tech Park. No.80,the 4th Avenue
FUJIAN SHANSHUI CHEMICAL CORP.LTD.

Contact:+86-151-59920036

Address:Jinqiao Gareden, jo@fj-xinyi.com
ORCHID CHEMICAL SUPPLIES LTD

website:http://www.orchid-chem.com

Contact:+86-571-85395792

Address:607, North Zhongshan Road, Hangzhou 310000 China
Hangzhou Donglou Bio-nutrient Co., Ltd.

Contact:+86-571-82225795,13967112289

Address:Louta Town, Xiaoshan,Hangzhou,Zhejiang

Relevant to this article

Synthesis of 1-amino-2,2-dialkylcyclopropanecarboxylic acids from β-chloroaldimines

Doi:10.1016/S0040-4020(01)86477-2
(1991)
Dual Stereocontrol for Enantioselective Hydrogenation of Dihydroisoquinolines Induced by Tuning the Amount of N-Bromosuccinimide

Doi:10.1002/cjoc.201700634
(2018)
The Crystal and Molecular Structure of cis-Dichloro<3,11-dimethyl-3,11,17,18-tetraazatricyclo<11.3.1.1^5,9>octadeca-1(17),5,7,9(18),13,15-hexaene>rhodium(III) Cation

Doi:10.1246/bcsj.63.1822
(1990)
Doi:10.1021/ja01632a094
(1954)
Antilipidemic agents, III: Synthesis of some heterocyclic derivatives of beta-sitosterol.

Doi:10.1002/ardp.19903230705
(1990)
Fluoroolefin dipeptide isosteres - II. Enantioselective synthesis of both antipodes of the Phe-Gly dipeptide mimic

Doi:10.1016/S0040-4039(00)88549-4
(1990)

Article Doi