Journal of Fluorine Chemistry p. 125 - 131 (1991)
Update date:2022-08-03
Topics:
Weigert, Frank J.
The major products from the cross-dimerization of butadiene and perfluorobutadiene are a 2+2-cycloadduct and a 2+4-cycloadduct.Perfluorobutadiene is the diene and butadiene is the dienophile.Minor products include the 4+4-cycloadduct, a criss-cross product, and several others containing fluorine on four membered rings.Pyrolysis converts both the 2+2- and the 2+4-adducts to the criss-cross product.Pyrolysis of the 2+2-adduct in the presence of carbon also gives 1,2,3- and 1,2,4-trifluorobenzenes.The fluorine nmr data for C4F6 cycloadducts helps assigning the structures.
View MoreHebei Kangtai Pharmaceutical Co.,Ltd
Contact:+86-0317-3512963
Address:Wugang Road,Mengcun of Cangzhou City,Hebei Province ,China
Suzhou Ryan Pharmachem Technology Co.,Ltd
Contact:+86-0512-68780025
Address:B-301,No.2 Taishan Road,Suzhou New District,Jiangsu,P.R. China
Contact:+86-27-85733560
Address:NO.308,QINGNIAN RD.,WUHAN,CHINA
Shanghai Mio Chemical Co., Ltd
Contact:0086 21- 64401188-622
Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Nanjing Vincero International Trading Co.,Ltd
Contact:8618936897229
Address:NO.68, ZhuShan Road, JiangNing WanDa Plaza, Building E Room 1703
Doi:10.1021/om2012584
(2012)Doi:10.1021/om201134j
(2012)Doi:10.1002/cjoc.201180354
(2011)Doi:10.1016/j.bmcl.2017.02.006
(2017)Doi:10.1002/jhet.802
(2012)Doi:10.1002/jhet.764
(2012)
