Helvetica Chimica Acta p. 1362 - 1368 (2010)
Update date:2022-07-30
Topics:
Yadav, Jhillu S.
Nageshwar Rao, Ragam
Somaiah, Ragam
Harikrishna, Valaboju
Subba Reddy, Basi V.
The stereocontrolled synthesis of goniothalesdiol A, a dihydroxylated tetrahydropyran compound, has been accomplished using d-ribose as chiral precursor. The key steps involved are aryl Grignard reaction, stereoselective alkoxy-directed keto reduction, and intramolecular oxy-Michael addition.
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