Mechanistic Analysis of the Reactions of (Pentafluorophenyl)nitrene in Alkanes

DOI: 10.1021/jo00022a036

Source and publish data:

Journal of Organic Chemistry p. 6403 - 6406 (1991)

Update date:2022-07-29

Topics:

Authors:

Young, Mary J. T.

Platz, Matthew, S.

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Article abstract of DOI:10.1021/jo00022a036

Photolysis of pentafluorophenyl azide in n-butane, cyclopentane, or 2,3-dimethylbutane releases singlet (pentafluorophenyl)nitrene, which can insert into a CH bond, ring expand to a ketenimine, or undergo intersystem crossing (ISC) to the triplet state of

Full text of DOI:10.1021/jo00022a036

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