
Tetrahedron Letters p. 3171 - 3174 (1991)
Update date:2022-08-02
Topics:
Crevisy
Beau
2,6-Diyne-4-cyclodecen-1-ol, a highly simplified and isolable monocyclic analogue of the bicyclic aglycone of esperamicins and calicheamicins, has been obtained by an intramolecular cyclocondensation of 1-iodo-1,5-diyne-3-decen-10-al mediated by chromium(II)-nickel(II) salts.
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