Novel Radical Chain Substitution Reaction Involving Single Electron Transfer Processes

DOI: 10.1021/jo00020a004

Source and publish data:

Journal of Organic Chemistry p. 5743 - 5745 (1991)

Update date:2022-07-30

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Authors:

Tamura, Rui

Yamawaki, Kunihiko

Azuma, Nagao

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Article abstract of DOI:10.1021/jo00020a004

β-Substituted α-<(phenylsulfonyl)methyl>- and α-<(phenylthio)methyl>cyclohexanones 1-4 underwent regioselective replacement of the sulfonyl and sulfenyl groups by stabilized carbanions such as LiCMe2NO2 mainly by a radical chain mechanism, which was confi

Full text of DOI:10.1021/jo00020a004

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