Chemische Berichte p. 77 - 82 (1997)
Update date:2022-07-30
Topics:
Garamszegi, Laszlo
Schlosser, Manfred
(Z)-(3,3-Dimethylbicyclo[2.2.1]hept-2-ylidene)methyllithium can be readily generated by treatment of (Z)-3-bromomethylene-2,2-dimethylbicyclo[2.2.1]heptane with ferf-butyl-lithium. At -75°C, the organometallic intermediate is configurationally stable and reacts with a variety of electrophiles under stereochemical retention. VCH Verlagsgesellschaft mbH,.
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