Tetrahedron p. 8353 - 8368 (1992)
Update date:2022-09-26
Topics: Migration Rearrangement Experimental Perfluoroalkyl 4-perfluoroalkyl-4-quinols 4-perfluoroalkyl-4-quinol rearrangement
Uno
Yayama
Suzuki
Heating a DMSO solution of 4-(perfluoro-n-alkyl)-4-hydroxy-2,5-cyclohexadien-1-one (4-perfluoroalkyl-4-quinols) in the presence of a catalytic amount of base brought about 1,2-migration of the perfluoroalkyl group to give 2-(perfluoro-n-alkyl)hydroquinone
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