Perfluoroalkyl migration in the rearrangement of 4-perfluoroalkyl-4-quinols

DOI: 10.1016/S0040-4020(01)86584-4

Source and publish data:

Tetrahedron p. 8353 - 8368 (1992)

Update date:2022-09-26

Topics: Migration Rearrangement Experimental Perfluoroalkyl

Authors:

Uno Uno

Yayama Yayama

Suzuki Suzuki

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Article abstract of DOI:10.1016/S0040-4020(01)86584-4

Heating a DMSO solution of 4-(perfluoro-n-alkyl)-4-hydroxy-2,5-cyclohexadien-1-one (4-perfluoroalkyl-4-quinols) in the presence of a catalytic amount of base brought about 1,2-migration of the perfluoroalkyl group to give 2-(perfluoro-n-alkyl)hydroquinone

Full text of DOI:10.1016/S0040-4020(01)86584-4

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