Tetrahedron Letters p. 3013 - 3016 (1991)
Update date:2022-08-03
Topics:
Kemp, D. S.
Buckler, David R.
The mixed disulfides from (R,S)-1-(Cbz-L-alanyloxy)-9-mercapto-phenoxathiin-10-sulfoxide and H-L-Cys-OMe undergo O,N-acyl transfer in DMSO at 23 deg C with rate constants of 7.0 h-1 and 0.048 h-1, and a rate ratio of 146; EM values of 0.2 M and 0.015 M.
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