Michael-type addition of secondary phosphine oxides to (1,4-cyclohexadien- 3-yl)phosphine oxides

Article abstract of DOI:10.1021/jo300026f

Base-induced reaction between (1,4-cyclohexadien-3-yl)phosphine oxides and secondary phosphine oxides gives 3,4-bis(phosphinoyl)cyclohexenes and 2,3-bis(phosphinoyl)cyclohexenes through an in situ isomerization of one of the cyclohexadienyl double bonds and a subsequent Michael-type addition of the secondary phosphine oxide.