Angewandte Chemie - International Edition p. 394 - 398 (2012)
Update date:2022-08-04
Topics:
Zhang, Xiaoming
Emge, Thomas J.
Hultzsch, Kai C.
If Grignard had only known! A chiral magnesium complex catalyzes the intramolecular hydroamination/cyclization of aminoalkenes with high efficiency at temperatures as low as -20 °C and enantioselectivities as high as 93 %ee. The high activity of this system also allows the catalytic intermolecular anti-Markovnikov addition of pyrrolidine and benzylamine to vinyl arenes. Copyright
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(2012)Doi:10.1021/om201276w
(2012)
