Synthese regioselective de silanes α-fonctionnels par alkylation du derive lithie du trimethylsilylacetonitrile

Article abstract of DOI:10.1016/0022-328X(91)86006-C

Lithiated trimethylsilylacetonitrile easily reacts, at -78 deg C, with various alyl bromides to lead to α-functional trimethylsilanes RCH(SiMe3)C<*>N, with R a saturated or unsaturated group.