Reaction of Tris(t-butylthio)cyclopropenylium Perchlorate with Arylmagnesium Bromides

DOI: 10.1246/bcsj.64.2298

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2298 - 2299 (1991)

Update date:2022-08-05

Topics:

Authors:

Kojima, Hideo

Ozaki, Kazuyoshi

Matsumura, Noboru

Inoue, Hiroo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.64.2298

The reaction of tris(t-butylthio)cyclopropenylium perchlorate with phenyl-, o-tolyl-, or 1-naphthylmagnesium bromide in tetrahydrofuran at room temperature gave t-butylthio-substituted allenes and indenes.The reaction with 2,6-xylylmagnesium bromide gave only the corresponding allene derivative.

Full text of DOI:10.1246/bcsj.64.2298

Products guided by the article

Product name:1-Methyl-2-(tris-tert-butylsulfanyl-propa-1,2-dienyl)-benzene

Cas No:136264-44-3

R&D Labs maybe for 136264-44-3

Huangshan Violet Biological Technology Co., Ltd

Contact:+86-559-2335676

Address:16-201 JinShanYuan,JiangNan New City,TunXi District,HuangShan City,AnHui Province,China
Shanghai Yuanye Bio-Technology Co., Ltd.

website:http://www.shyuanye.com

Contact:+86-21-61845781

Address:Building 6, No. 465, Changta Road,Songjiang District,Shanghai,China
Shanghai Taibao Pharmaceutical Technology Co., Ltd(expird)

Contact:021-52217366

Address:shanghai
hangzhou sunchem trading co., ltd.

Contact:13588470430--

Address:Room 406-407, the 4th Building, No549
Zibo Ocean International Trade Co.,Ltd(expird)

Contact:+86 533 5160706

Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China

Relevant to this article

One-pot oxidative Ugi-type three-component reaction of aromatic hydrocarbons of petroleum naphtha: comparing catalytic effect of cellulose- and wool-SO₃H supported with manganese dioxide nanostructures

Doi:10.1039/c5ra16608j
(2015)
Pd-catalysed synthesis of isoquinolinones and analogues via C-H and N-H bonds double activation

Doi:10.1039/c2cc17859a
(2012)
Synthesis of Erythrina and related alkaloids. XXIV. Total synthesis of erysotrine from 1,7-cycloerythrinan derivatives by the use of a new 1,2-carbonyl transposition method

Doi:10.1248/cpb.39.1365
(1991)
Synthesis of bis(halovinyl)benzenes by catalytic olefination

Doi:10.1007/s11172-013-0091-4
()
EQUILIBRIUM CH ACIDITY OF ARYLACETYLENES IN DIMETHYL SULFOXIDE

Doi:10.1007/BF00947852
(1984)
PEROXO AND ALKYLPEROXIDIC MOLYBDENUM(VI) COMPLEXES AS INTERMEDIATES IN THE EPOXIDATION OF OLEFINS BY ALKYL HYDROPEROXIDES

Doi:10.1016/0022-328X(83)85059-1
(1983)

Article Doi