Reaction of Tris(t-butylthio)cyclopropenylium Perchlorate with Arylmagnesium Bromides

DOI: 10.1246/bcsj.64.2298

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2298 - 2299 (1991)

Update date:2022-08-05

Topics:

Authors:

Kojima, Hideo

Ozaki, Kazuyoshi

Matsumura, Noboru

Inoue, Hiroo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.64.2298

The reaction of tris(t-butylthio)cyclopropenylium perchlorate with phenyl-, o-tolyl-, or 1-naphthylmagnesium bromide in tetrahydrofuran at room temperature gave t-butylthio-substituted allenes and indenes.The reaction with 2,6-xylylmagnesium bromide gave only the corresponding allene derivative.

Full text of DOI:10.1246/bcsj.64.2298

Products guided by the article

Product name:1-Methyl-2-(tris-tert-butylsulfanyl-propa-1,2-dienyl)-benzene

Cas No:136264-44-3

R&D Labs maybe for 136264-44-3

Shanghai Haoyuan Chemexpress Co., Ltd.

website:https://www.chemexpress.com/

Contact:86-21-58950125

Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203
LIAONING DMSO CHEMICALS CO.,LTD.

website:http://www.chinadmso.com

Contact:+86-427-6503033

Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA
Chinapeptides Co,. Ltd

Contact:+86-021-50792271

Address:Building 24A, 300 Chuantu Road, Chuansha, Pudong new area, Shanghai, China, 201202
Wuxi Morality Chemical Co., Ltd(expird)

Contact:

Address:B/7F, 321th WuYun Rd, Wanda Plaza, Wuxi City, 214174, China
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-5161 3915

Address:Shanghai YangPu

Relevant to this article

One-pot oxidative Ugi-type three-component reaction of aromatic hydrocarbons of petroleum naphtha: comparing catalytic effect of cellulose- and wool-SO₃H supported with manganese dioxide nanostructures

Doi:10.1039/c5ra16608j
(2015)
Pd-catalysed synthesis of isoquinolinones and analogues via C-H and N-H bonds double activation

Doi:10.1039/c2cc17859a
(2012)
Synthesis of Erythrina and related alkaloids. XXIV. Total synthesis of erysotrine from 1,7-cycloerythrinan derivatives by the use of a new 1,2-carbonyl transposition method

Doi:10.1248/cpb.39.1365
(1991)
Synthesis of bis(halovinyl)benzenes by catalytic olefination

Doi:10.1007/s11172-013-0091-4
()
EQUILIBRIUM CH ACIDITY OF ARYLACETYLENES IN DIMETHYL SULFOXIDE

Doi:10.1007/BF00947852
(1984)
PEROXO AND ALKYLPEROXIDIC MOLYBDENUM(VI) COMPLEXES AS INTERMEDIATES IN THE EPOXIDATION OF OLEFINS BY ALKYL HYDROPEROXIDES

Doi:10.1016/0022-328X(83)85059-1
(1983)

Article Doi