Bulletin of the Chemical Society of Japan p. 2298 - 2299 (1991)
Update date:2022-08-05
Topics:
Kojima, Hideo
Ozaki, Kazuyoshi
Matsumura, Noboru
Inoue, Hiroo
The reaction of tris(t-butylthio)cyclopropenylium perchlorate with phenyl-, o-tolyl-, or 1-naphthylmagnesium bromide in tetrahydrofuran at room temperature gave t-butylthio-substituted allenes and indenes.The reaction with 2,6-xylylmagnesium bromide gave only the corresponding allene derivative.
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