Reaction of Tris(t-butylthio)cyclopropenylium Perchlorate with Arylmagnesium Bromides

DOI: 10.1246/bcsj.64.2298

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2298 - 2299 (1991)

Update date:2022-08-05

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Authors:

Kojima, Hideo

Ozaki, Kazuyoshi

Matsumura, Noboru

Inoue, Hiroo

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Article abstract of DOI:10.1246/bcsj.64.2298

The reaction of tris(t-butylthio)cyclopropenylium perchlorate with phenyl-, o-tolyl-, or 1-naphthylmagnesium bromide in tetrahydrofuran at room temperature gave t-butylthio-substituted allenes and indenes.The reaction with 2,6-xylylmagnesium bromide gave only the corresponding allene derivative.

Full text of DOI:10.1246/bcsj.64.2298

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