Journal of the American Chemical Society p. 4573 - 4576 (2012)
Update date:2022-07-30
Topics:
Ros, Abel
Lopez-Rodriguez, Rocio
Estepa, Beatriz
Alvarez, Eleuterio
Fernandez, Rosario
Lassaletta, Jose M.
The use of hemilabile pyridine-hydrazone N,N-ligands allows the highly selective Ir-catalyzed ortho,ortho'-directed diborylation of aromatic N,N-dimethylhydrazones in near-quantitative yields. One-pot sequential Suzuki-Miyaura cross-coupling with different aryl bromides provides a short entry to unsymmetrically substituted 2,6-diarylbenzaldehyde derivatives.
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(2012)
