Chinese Chemical Letters p. 313 - 316 (2012)
Update date:2022-07-29
Topics:
Rong, Shao Feng
Zhang, Xiao Li
Ding, Bao Mei
Wang, Yi Fei
Pan, Xian Hua
Zhang, Jian
Shen, Yi
Canrenone (1) was biotransformed into 11α-hydroxycanrenone (2) and a main byproduct (3) by Aspergillus ochraceus SIT34205. Compound 3 was separated and purified using silica gel column chromatography, and its structure was characterized via MS and NMR methods. These results indicated that 3 was 1β,11α-dihydroxycanrenone and the product of further hydroxylation of 2. Thus, investigating the structure and synthesis of 3 may be a promising method to improve the efficiency and purity of 2.
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Doi:10.1007/BF00810468
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