Welcome to LookChem.com Sign In|Join Free

Article Doi

Synthesis, Spectroscopic and X-Ray Structural Characterization of Ternary Complexes of Copper(II) and 2,5-Dimethoxycinnamic Acid with Phenanthrolines

DOI: 10.1039/DT9910002109

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2109 - 2112 (1991)

Update date:2022-08-04

Topics:

Authors:

Battaglia, Luigi PietroBattaglia, Luigi Pietro

Corradi, Anna BonamartiniCorradi, Anna Bonamartini

Zoroddu, Maria AntoniettaZoroddu, Maria Antonietta

Manca, GavinaManca, Gavina

Basosi, RiccardoBasosi, Riccardo

Solinas, CostantinoSolinas, Costantino

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9910002109

The complexes were synthesised and characterized by magnetic measurements, EPR and reflectance electronic spectroscopy.The crystal structure of has been determined by X-ray diffraction: it consists of discrete units in which a very asymmetric CuN2O2O'2 chromophore is present with the two nitrogen atoms from 2,9-dmphen nearly symmetrically chelated , two carboxylic oxygens of a bidentate dmc molecule , and the oxygen atom of a monodentate carboxylic acid group of a second dmc molecule.Copper deviates from the 2,9-dmphen plane by 0.1811(7) Angstroem and the carboxylic acid groups lie on planes roughly orthogonal <92.1(3) deg>; the second carboxylic oxygen of the monodentate dmc molecule is involved in a long contact with the metal .

View More

Products guided by the article

Product name:{Cu(dmc)2(2,9-dmphen)}

Cas No:136541-24-7

136541-24-7

R&D Labs maybe for 136541-24-7

Relevant to this article

Hot Product