Journal of the Chemical Society. Perkin Transactions 1 (2001) p. 3519 - 3521 (2000)
Update date:2022-08-04
Topics:
Liu, Zhi-Yu
Ji, Jian-Xin
Li, Bo-Gang
The conversion of racemic terminal epoxides into either (+)- or (-)-diol γ-and δ-lactones was described with hydrolytic kinetic resolution (HKR). The optically active epoxide and diol were isolated together from the reaction mixture by bulb-to-bulb distillation. The HKR of racemic terminal epoxides gave active epoxides and diols which were converted into the corresponding lactones.
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