Intramolecular SH2 macrocyclisations

DOI: 10.1016/S0040-4020(01)86541-8

Source and publish data:

Tetrahedron p. 5901 - 5918 (1991)

Update date:2022-08-05

Topics:

Authors:

Baldwin, Jack E.

Adlington, Robert M.

Mitchell, Mark B.

Robertson, Jeremy

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Article abstract of DOI:10.1016/S0040-4020(01)86541-8

The synthesis of 10-15 membered α-methylene macrocyclic lactones from the functionalised allylstannanes (7e)-(7j) is described. Attempts to synthesise analogous 6-9 membered lactones proved unsuccessful, resulting instead in the production of dilactones and AIBN derived adducts.

Full text of DOI:10.1016/S0040-4020(01)86541-8

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