Synthesis and evaluation in asymmetric hydrogenation of carbohydrate-derived 1,3-bisphosphines

DOI: 10.1016/0008-6215(92)84158-O

Source and publish data:

Carbohydrate Research p. 149 - 169 (1991)

Update date:2022-07-29

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Authors:

Li, Chunbao

Bernet, Bruno

Vasella, Andrea

Broger, Emil A.

Meili, Arthur

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Article abstract of DOI:10.1016/0008-6215(92)84158-O

1,3-Bisphosphines and 1,3-phosphine sulfides have been prepared from 1,6-anhydro-β-D-glucopyranose in view of their application as bidentate ligands in transition-metal-catalyzed asymmetric hydrogenation.Reaction of 1,6:3,4-dianhydro-2-O-(p-toluenesulfony

Full text of DOI:10.1016/0008-6215(92)84158-O

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Product name:1,6-anhydro-4-deoxy-4-(diphenylphosphoryl)-2-O-(p-toluenesulfonyl)-β-D-glucopyranose

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