Studies directed toward the total synthesis of tetronolide 1. An enantioselective synthesis of the octahydronaphthalene unit

DOI: 10.1016/S0040-4039(00)79871-6

Source and publish data:

Tetrahedron Letters p. 4091 - 4094 (1991)

Update date:2022-08-04

Topics:

Authors:

Boeckman Jr., Robert K.

Barta, Thomas E.

Nelson, Scott G.

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Article abstract of DOI:10.1016/S0040-4039(00)79871-6

An efficient enantioselective route to the octahydronaphthalene unit present in tetronolide (1), the stereochemically complex aglycone common to the tetrocarcins, a novel group of antitumor substances, is described. The sequence employs the intramolecular

Full text of DOI:10.1016/S0040-4039(00)79871-6

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Product name:1-(3-{(1S,2S,4aS,5S,6S,8S,8aR)-2-[(E)-3-(4-Methoxy-benzyloxy)-1-methyl-propenyl]-5-methoxymethoxy-1,6,8-trimethyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalen-1-yl}-3-oxo-propionyloxy)-cyclohexanecarboxylic acid methyl ester

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