Regiospecific Palladium-Catalyzed Cycloaddition of Aziridines and Carbodiimides

DOI: 10.1021/jo00027a030

Source and publish data:

Journal of Organic Chemistry p. 157 - 162 (1992)

Update date:2022-07-29

Topics: Palladium Carbodiimides Cycloaddition Aziridines Regiospecific

Authors:

Baeg, Jin-Ook

Alper, Howard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00027a030

Bis(benzonitrile)palladium dichloride is an effective catalyst for the cycloaddition reaction of aziridines with carbodiimides to form imidazolidinimines in 40-94 percent yields.The process is a regiospecific one, involving cleavage of the more substitute

Full text of DOI:10.1021/jo00027a030

Products guided by the article

Product name:[4-(4-Bromo-phenyl)-1-tert-butyl-3-p-tolyl-imidazolidin-(2Z)-ylidene]-p-tolyl-amine

Cas No:136912-62-4

R&D Labs maybe for 136912-62-4

Angelisun(Chongqing) Pharmaceutical Co., LTD.

Contact:+86-23-68030926-816

Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
Clearsynth Labs Limited

Contact:+91 - 22 - 26355700

Address:17, Lotus Business Park, Andheri West
Shanghai Kefu Chemical Co.,Ltd.

Contact:+86-21-34616196

Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Arromax Pharmatech Co.,Ltd

website:http://www.arromax.com

Contact:+86-0512-62959601 skype:aimmezhang

Address:Suite 401, Bldg A3, 218 Xinghu St.Suzhou Industrial Park 215123, P.R. China
Jiangxi Hessence Chemicals Co., Ltd.

Contact:+86 796 3511924

Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.

Relevant to this article

Combinatorial aid for underprivileged scaffolds: Solution and solid-phase strategies for a rapid and efficient access to novel aza-diketopiperazines (aza-DKP)

Doi:10.1021/co300015k
(2012)
A convenient and mild chromatography-free method for the purification of the products of Wittig and Appel reactions

Doi:10.1039/c2ob07074j
(2012)
Synthesis and bioactivity of substituted benzoylguanidine derivatives as potent Na⁺/H⁺ exchanger inhibitors

Doi:10.1002/cjoc.201180470
(2012)
Syntheses and X-ray crystal structures of cassiferaldehyde and analogs

Doi:10.1080/00397911.2010.523921
(2012)
Dendrimeric amide- and carbamate-linked lysine-based efficient molecular transporters

Doi:10.1039/c7ob02552a
(2017)
Direct palladium(II)-catalyzed synthesis of arylamidines from aryltrifluoroborates

Doi:10.1021/ol300813c
(2012)

Article Doi