BIS(TERT-BUTYLSULFONYL)ACETYLENE AS A GENERAL SYNTHETIC EQUIVALENT OF ALKYNES IN DIELS-ALDER CHEMISTRY. II: REDUCTIVE AND ALKYLATIVE DESULFONYLATIONS OF BICYCLIC 1-ALKYL-2-(TERT-BUTYLSULFONYL)ETHENES

DOI: 10.1016/0040-4039(91)80045-8

Source and publish data:

Tetrahedron Letters p. 4583 - 4586 (1991)

Update date:2022-09-26

Topics:

Authors:

Virgili, Marina

Belloch, Jordi

Moyano, Albert

Pericas, Miquel A.

Riera, Antoni

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Article abstract of DOI:10.1016/0040-4039(91)80045-8

Both reductive and alkylative desulfonylations of bicyclic vinyl sulfones derived from Diels-Alder cycloadducts of bis(tert-butylsulfonyl)acetylene (1) are described.These transformations establish the synthetic equivalence of 1 with acetylene, 1-alkynes

Full text of DOI:10.1016/0040-4039(91)80045-8

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