Preparation of racemic and chiral alkyl (1,3-butadien-2-yl)methanol derivatives ut,ilizing 1-trimethylsilyl-2,3-butadiene as a diene source

DOI: 10.1016/0040-4039(91)80026-3

Source and publish data:

Tetrahedron Letters p. 4509 - 4512 (1991)

Update date:2022-07-30

Topics:

Authors:

Hatakeyama, Susumi

Sugawara, Kazutoshi

Kawamura, Mitsuhiro

Takano, Seiichi

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Article abstract of DOI:10.1016/0040-4039(91)80026-3

Ti(IV) chloride mediated reaction of 1-trimethylsilyl-2,3-butadiene with various aldehydes and acetals has been examined establishing an efficient method for the preparation of alkyl(1,3-butadien-2-yl)methanols. Application of this method to chiral acetal

Full text of DOI:10.1016/0040-4039(91)80026-3

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