Angewandte Chemie - International Edition p. 2142 - 2145 (2012)
Update date:2022-09-26
Topics:
Bhar, Kishalay
Khan, Sumitava
Costa, Jose Sanchez
Ribas, Joan
Roubeau, Olivier
Mitra, Partha
Ghosh, Barindra Kumar
All in a spin: A cobalt(II) coordination polymer has a highly cooperative spin-crossover (SCO) behavior with a small hysteresis loop (see picture; HS=high spin, LS=low spin). The correlation of the magnetic properties with the crystal structures was determined at different temperatures. This study reveals an unprecedented reversible symmetry breaking in a d7 SCO coordination polymer. Copyright
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