Glycosylidene Carbenes Part 4 Synthesis of Spirocyclopropanes from Acetamidoglycosylidene-Derived Diazirines

DOI: 10.1002/hlca.19910740625

Source and publish data:

Helvetica Chimica Acta p. 1362 - 1372 (1991)

Update date:2022-08-03

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Authors:

Vasella, Andrea

Witzig, Christian

Husi, Rene

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Article abstract of DOI:10.1002/hlca.19910740625

The synthesis of the first glycosylidene-derived 2-acetamido-2-deoxydiazirine 4 from N-acetylglucosamine 6 is described.Thus, 6 was transformed into the 3-O-mesylglucopyranoside 9 by glycosidation with allyl alcohol, benzylidenation, and mesylation (Schem

Full text of DOI:10.1002/hlca.19910740625

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