Highly Regioselective Ring Opening of 2,3-Epoxy Alcohol Methanesulfonates

DOI: 10.1246/cl.1991.1787

Source and publish data:

Chemistry Letters p. 1787 - 1790 (1991)

Update date:2022-08-05

Topics:

Authors:

Gao, Lian-xun

Saitoh, Hitoshi

Feng, Fei

Murai, Akio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1991.1787

Reaction of 2,3-epoxy-1-ol methanesulfonates with diethylaluminum chloride or with the mixture of diethylaluminum chloride and diethylamine hydrobromide in dichloromethane gave rise to regioselectively the corresponding 3-chloro- and 3-bromo-1,2-diol 1-methanesulfonates, respectively, in excellent yields.

Full text of DOI:10.1246/cl.1991.1787

Products guided by the article

Product name:Methanesulfonic acid 3-chloro-2-hydroxy-3-phenyl-propyl ester

Cas No:137369-70-1

R&D Labs maybe for 137369-70-1

SHAANXI TOP PHARM CHEMICAL CO.LTD

Contact:+86-029-85733403

Address:No.108 ,west sector,south er huan,xi'an,china
Nanjing Fayekong Chemcial Co.,Ltd(expird)

Contact:86-25-58813444

Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
Taizhou Chemedir Biopharm-tech Co., Ltd

Contact:+86 523 86200218

Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
Yantai Derun Liquid Crystal Materials Co. Ltd.

website:http://www.ytderun.com

Contact:86-535-6300169

Address:ROOM 90, XIANGFU STREET, FUSHAN NEW-HIGH-TECH IDUSTRY ZONE, YANTAI
Anhui Jiatiansen Agrochemical Co.,Ltd

Contact:15366811918

Address:chemical industrial park,xiangyu town,dongzhi county,anhui,china

Relevant to this article

Stereoselective Synthesis of <3.3.0> Fused Lactones (γ-Butyrolactones) of Sugars and Nucleosides by Free Radical Intramolecular Cyclization

Doi:10.1039/c39910001263
(1991)
"conformation Locked" Strong Electron-Deficient Poly(p -Phenylene Vinylene) Derivatives for Ambient-Stable n-Type Field-Effect Transistors: Synthesis, Properties, and Effects of Fluorine Substitution Position

Doi:10.1021/ja412533d
(2014)
1-Benzyl-3,3,5′,6′-tetramethylspiro[indoline-2,2′-[2H] pyrano[3,2-b]- pyridinium] iodide, its hydrate, and a neutral precursor of the salts: Synthesis, crystal structure, photochromic transformations in solutions and in crystals

Doi:10.1007/s11172-011-0210-z
(2011)
Reporting the release of caged species by a combination of two sequential photoreactions, a molecular switch, and one color of light

Doi:10.1002/anie.201108336
(2012)
Transferrin-modified c[RGDfK]-paclitaxel loaded hybrid micelle for sequential blood-brain barrier penetration and glioma targeting therapy

Doi:10.1021/mp200600t
(2012)
Catalytic asymmetric ±-acylation of tertiary amines mediated by a dual catalysis mode: N-heterocyclic carbene and photoredox catalysis

Doi:10.1021/ja3030164
(2012)

Article Doi