Tetrahedron Letters p. 5417 - 5420 (1991)
Update date:2022-08-03
Topics:
Coulter, Thomas
Grigg, Ronald
Malone, John F.
Sridharan, Visuvanathar
Cyclic secondary α-amino acids react with isatin and menthyl acrylate via decarboxylative azomethine ylide formation and subsequent cycloaddition involving an endo-transition state to give cycloadducts in 67-82percent d.e.The stereochemistry of the major cycloadduct is assigned from a single crystal X-ray structure and a transition state model is proposed for the process. Key Words: 1,3-Dipole; cycloaddition; decarboxylation; chiral induction.
View MoreNanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
MedicalChem(Yancheng)Manuf.Co.,Ltd.
Contact:+86-515-84383366
Address:Touzeng BinHai, YanCheng City, JiangSu Province, China
Shanghai Pinewood Fine Chemical Co., Ltd.
website:http://www.pinewoodchem.com
Contact:0086-21-62417129，62414096
Address:Suite B, 27F, No.2, Lane 600, Tianshan Road, Shanghai
shijiazhuang baisheng chem co.; ltd
Contact:86-0311-80790826
Address:shijiazhuang hebei
Tianjin Tongde Biological Technology Co., Ltd.
Contact:86-22-23309138
Address:Room 402, bulidingE3 Detection certification park, XiQingDistrict, Tianjin City
Doi:10.3762/bjoc.8.28
(2012)Doi:10.1002/anie.202006720
(2020)Doi:10.1021/jo0157472
(2002)Doi:10.1055/s-0037-1611731
(2019)Doi:10.1016/S0040-4020(99)00209-4
(1999)Doi:10.1080/10426509708043496
(1997)
