Selective monoalkylation of acyclic diols by means of dibutyltin oxide and fluoride salts

DOI: 10.1248/cpb.39.1972

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1972 - 1982 (1991)

Update date:2022-07-29

Topics:

Authors:

Nagashima

Ohno Ohno

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.39.1972

Fluoride anion was found to promote monoalkylation reaction of diols by the stannylene acetal method, and selective monoalkylation of various acyclic diols was accomplished in good yields under mild conditions by employing this new method. Functional groups such as carboxylic acid ester, carboxamide, carbamate, nitrile, alkyl chloride, and ether were not affected under the reaction conditions.

Full text of DOI:10.1248/cpb.39.1972

NII-Electronic Library Service

Products guided by the article

Product name:N-methyl-2-hydroxy-3-(benzyloxy)propionamide

Cas No:137618-56-5

R&D Labs maybe for 137618-56-5

ANHUI WEICHI CHEMICAL CO.,LTD

website:http://www.weichichem.com

Contact:+8613912949432

Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
Shanghai united Scientific Co.,Ltd.

Contact:+86-21-53535353

Address:28F No.900 huaihai Road Shanghai China
Wuhan Chemchemical Co., Ltd.(expird)

Contact:15973022782

Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.
Quzhou Hopemax Chemical Technology Co.Ltd

Contact:86-570-3036007

Address:Room 801,Building 2,Wealth Center,No.51,Xujiang Road,Quzhou,China.
Changzhou Ansciep Chemical Co.,Ltd.

Contact:+86 519 8630 5871

Address:A-710 Boan International, 8 East Guangdian Road,Wujin,Changzhou

Relevant to this article

A new class of organosuperbases, N-alkyl- and N-aryl-1,3-dialkyl-4,5- dimethylimidazol-2-ylidene amines: Synthesis, structure, pK_BH+ measurements, and properties

Doi:10.1002/chem.201102249
(2012)
New octahedral, head-tail iron(II) complexes with spin crossover properties

Doi:10.1002/ejic.201101096
(2012)
Scalable synthesis of cladosporin

Doi:10.1016/j.tetlet.2019.02.012
(2019)
Copper(I)-catalyzed asymmetric desymmetrization: Synthesis of five-membered-ring compounds containing all-carbon quaternary stereocenters

Doi:10.1021/ja3032345
(2012)
New methodology for the synthesis of thiobarbiturates mediated by manganese(III) acetate

Doi:10.3390/molecules17044313
(2012)
Carbocycles from carbohydrates: Synthesis of some polyfunctionauzed cyclohexane derivatives. Preparation of useful chiral building blocks

Doi:10.1016/S0040-4020(01)88289-2
(1991)

Article Doi