A CONVENIENT SYNTHESIS OF FLUORINATED α,β-UNSATURATED AMIDES

DOI: 10.1016/S0022-1139(00)80965-3

Source and publish data:

Journal of Fluorine Chemistry p. 429 - 436 (1991)

Update date:2022-08-03

Topics:

Authors:

Shen, Yanchang

Xiang, Yuejun

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Article abstract of DOI:10.1016/S0022-1139(00)80965-3

Pentafluorophenylated or p-chloro-tetrafluorophenylated α,β-unsaturated amides could be synthesized by the reaction of fluorinated arsorane, generated in situ from methylenetriphenylarsorane and hexafluorobenzene or chloro-pentafluorobenzene, with α-bromoacetamides in good yields giving E-isomer exclusively.

Full text of DOI:10.1016/S0022-1139(00)80965-3

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Product name:(E)-N,N-Diethyl-3-pentafluorophenyl-acrylamide

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