EPIMERIZATION OF 2,4-DIBENZYLIDENE-6-METHYLBICYCLOHEXAN-3-ONE

DOI: 10.1016/S0040-4039(00)79413-5

Source and publish data:

Tetrahedron Letters p. 5869 - 5872 (1991)

Update date:2022-09-26

Topics:

Authors:

Kearley, Mark L.

Lahti, Paul M.

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Article abstract of DOI:10.1016/S0040-4039(00)79413-5

Thermal epimerization of the title compound occurs readily at > 150 deg C, with Eyring parameters of ΔH(excit.) = 29.8 kcal/mol and ΔS(excit.) = -10.8 kcal/mol-K, consistent with a planarized intermediate or transition state.

Full text of DOI:10.1016/S0040-4039(00)79413-5

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