Insertion of Mercury into Iron-Halogen Bonds. X-Ray Structure of HgI2>

DOI: 10.1039/DT9910002503

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2503 - 2510 (1991)

Update date:2022-08-05

Topics:

Authors:

Coco, Silverio

Espinet, Pablo

Mayor, Fernando

Solans, Xavier

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9910002503

The complexes (R = Ph, p-MeC6H4 or Bu^t) react with Hg in the presence of CNR to give <(RNC)5Fe->HgI2>, and exchange reactions with AgX (X = Br or Cl) lead to the corresponding halogeno-complexes <(RCN)5Fe->HgX2>.Treatment with 1 mol of AgClO4 affords the cationic complexes <(RNC)5Fe-HgX>ClO4 which are unstable towards mercury extrusion.The relative stability of the complexes is discussed in terms of the influence of the ligands co-ordinated to Hg and the steric and electronic characteristics of the RNC ligands.The structure of <(p-MeC6H4NC)5Fe->HgI2> has been determined: monoclinic, space group P2₁/a, a = 16.680(3), b = 18.031(4), c = 15.256(2) Angstroem, β = 116.92(2) deg and Z = 4.

Full text of DOI:10.1039/DT9910002503

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Iron, pentakis(1-isocyano-4-methylbenzene)-

Cas No:137914-99-9

R&D Labs maybe for 137914-99-9

SHANGHAI GILEADER ADVANCE MATERIAL TECHNOLOGY CO.,LTD

website:http://www.tanguitech.com/contact.asp

Contact:+86-021-58692556

Address:No.6 Building,No. 668 Hengan RD Pudong,Shanghai
Anhui New Star Pharmaceutical Development Co., Ltd

Contact:013956922763

Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China
xuri chemicals co., ltd

Contact:86-516-66656369

Address:The west road of Huaihai, Xuzhou, China
Zibo Fuxi'er Chemical Co.,Ltd （Shanxian Fuxi'er Chemical Co.,Ltd）

Contact:+86-533-2091422

Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China
Ji'nan Orgachem Pharmaceutical Co.,Ltd

Contact:+86-531-82687810

Address:Jinan

Relevant to this article

Indium-catalyzed cycloisomerizations of cyclopropene-3,3-dicarbonyl compounds: Efficient access to benzo-fused heteroaromatics and heterobiaryls

Doi:10.1002/anie.201107717
(2012)
Acetylphosphonate as a surrogate of acetate or acetamide in organocatalyzed enantioselective aldol reactions

Doi:10.1021/ol301270w
(2012)
Cyclisation chemistry of some functionalised allylsilanes

Doi:10.1016/S0040-4020(01)88293-4
(1991)
Expeditious synthesis of multisubstituted indoles: Via multiple hydrogen transfers

Doi:10.1039/c8cc07009a
(2018)
Sulfonated rice husk ash (RHA-SO₃H) as a highly efficient and reusable catalyst for the synthesis of some bis-heterocyclic compounds

Doi:10.1039/c3ra44053b
(2013)
A crossover from rod-shaped to bent-shaped in symmetric isoflavone liquid crystal trimers exhibiting unusual mesomorphic behaviour

Doi:10.1039/c2jm30943b
(2012)

Article Doi