Journal of the American Chemical Society p. 11876 - 11879 (2015)
Update date:2022-08-03
Topics:
Spangler, Jillian E.
Kobayashi, Yoshihisa
Verma, Pritha
Wang, Dong-Hui
Yu, Jin-Quan
Pd(II)-catalyzed α-C(sp3)-H arylation of pyrrolidines, piperidines, azepanes, and N-methylamines with arylboronic acids has been developed for the first time. This transformation is applicable to wide arrays of pyrrolidines and boronic acids, including heteroaromatic boronic acids. A diastereoselective one-pot heterodiarylation of pyrrolidines has also been achieved.
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