Synthetic transformations of higher terpenoids. XXVII.* synthesis of 7-hydroxylabdanoids and their transformations

DOI: 10.1007/s10600-012-0215-3

Source and publish data:

Chemistry of Natural Compounds p. 250 - 257 (2012)

Update date:2022-08-05

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Authors:

Kharitonov

Shul'ts Shul'ts

Gatilov Gatilov

Bagryanskaya

Shakirov

Tolstikov

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Article abstract of DOI:10.1007/s10600-012-0215-3

Allylic oxidation of phlomisoic acid and its methyl ester by selenium dioxide occurred stereoselectively to form 7α-hydroxy derivatives of labdanoids, which were oxidized by active manganese dioxide to 7-ketofuranolabdanoids. Oximation of the last by hydr

Full text of DOI:10.1007/s10600-012-0215-3

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