cC5Me5)>P=Mn(CO)4: Ein stabiler λ4-Phosphandiyl-Komplex mit Phosphor-Mangan-Mehrfachbindung

DOI: 10.1016/0022-328X(91)86355-T

Source and publish data:

Journal of Organometallic Chemistry p. C9 - C13 (1991)

Update date:2022-07-30

Topics:

Authors:

Lang, Heinrich

Leise, Michael

Emmerich, Christiane

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Article abstract of DOI:10.1016/0022-328X(91)86355-T

The reaction of (2,4,6-t-Bu3C6H2O)(^cC5Me5)P(Cl), I, with NaMn(CO)5, II, affords in 90percent yield the terminal neutral phosphenium ion complex <(2,4,6-t-Bu3C6H2O)(^cC5Me5)>P=Mn(CO)4, III.III is an example of a stable λ-phosphanediyl

Full text of DOI:10.1016/0022-328X(91)86355-T

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