Tetrahedron Letters p. 5895 - 5898 (1991)
Update date:2022-08-03
Topics:
Katz, Thomas J.
Yang, Ginger Xu-Quiang
Adsorbed on silica-gel or on other adsorbants (MgSO4, Na2SO4, or Na2CO3), but not in homogeneous solution, pentacarbonyl(methoxyethylidene)chromium combines with simple enynes to give bicyclo<3.1.0>hexanes.The method's usefulness is illustrated by the synthesis of a variaty of previously unknown structures from simple hydrocarbons, ethers, and amines.
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