Inversion of the Ground-State Spin Multiplicity by Electron-Withdrawing Groups in Trimethylenemethane Derivatives Generated Photochemically from Methylenequadricyclane Derivatives

DOI: 10.1021/jo00029a018

Source and publish data:

Journal of Organic Chemistry p. 876 - 882 (1992)

Update date:2022-08-03

Topics:

Authors:

Hirano, Takashi

Kumagai, Tsutomu

Miyashi, Tsutomu

Akiyama, Kimio

Ikegami, Yusaku

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00029a018

An inversion of the ground-state spin multiplicity of trimethylenemethane (TMM) by electron-withdrawing groups was investigated by EPR spectroscopy, for a series of TMMs 2b-g generated photochemically from methylenequadricyclanes 1b-g.Curie law analyses b

Full text of DOI:10.1021/jo00029a018

Products guided by the article

Product name:3-(Cyanophenylmethylene)tetracyclo<3.2.0.0^2,7.0^4,6>heptane

Cas No:138062-43-8

R&D Labs maybe for 138062-43-8

Shanghai UCHEM Inc.

Contact:+86-21-56338808

Address:799 Dunhuang Road, Putuo
Xinxiang Junlong Biological Technology Co., Ltd.

website:https://junlongbio.lookchem.com/

Contact:86-13525059581

Address:Xinxiang City, Henan Province
Jiangyin Tenghua Import&Export Co.,Ltd.

Contact:+86-510-86263875

Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road
Nanjing Chemzam Pharmtech Co., Ltd.

Contact:+86-25-86462165,+86-13915979898

Address:C5-1，6 Maiyue Road，Maigaoqiao，Nanjing，Jiangsu，China

Relevant to this article

Doi:10.1021/ja01623a068
(1955)
Doi:10.1246/bcsj.50.197
(1977)
Novel "Potentially Antiaromatic", Acidichromic Quinonediimines with Tunable Delocalization of Their 6π-Electron Subunits

Doi:10.1021/ja035463u
(2003)
Doi:10.1021/jo01282a036
(1967)
Preparation of high specific activity all trans α retinyl 11 ³H acetate

Doi:10.1002/jlcr.2580130113
(1977)
Doi:10.1021/jm00333a031
(1964)

Article Doi