Inversion of the Ground-State Spin Multiplicity by Electron-Withdrawing Groups in Trimethylenemethane Derivatives Generated Photochemically from Methylenequadricyclane Derivatives

DOI: 10.1021/jo00029a018

Source and publish data:

Journal of Organic Chemistry p. 876 - 882 (1992)

Update date:2022-08-03

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Authors:

Hirano, Takashi

Kumagai, Tsutomu

Miyashi, Tsutomu

Akiyama, Kimio

Ikegami, Yusaku

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Article abstract of DOI:10.1021/jo00029a018

An inversion of the ground-state spin multiplicity of trimethylenemethane (TMM) by electron-withdrawing groups was investigated by EPR spectroscopy, for a series of TMMs 2b-g generated photochemically from methylenequadricyclanes 1b-g.Curie law analyses b

Full text of DOI:10.1021/jo00029a018

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