Tetrahedron Letters p. 5927 - 5930 (1991)
Update date:2022-08-02
Topics:
Gmeiner, Peter
Bollinger, Bernd
A mild and efficient method for the construction of β-aryl amines from the corresponding α-aryl ketones is presented.The key step of the synthesis involve an electrophilic amination by dibenzyl azodicarboxylate followed by a stereoselective LiHBEt3 reduction.The reaction sequence is applied to the synthesis of the tricyclic ergoline analogue 4. Key words: electrophilic amination; stereoselective reduction; α-amino ketones.
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