Silver(I) Catalyzed Amino Cyclization of O-(2,3-Butadienyl) Carbamates: An Efficient and Stereoselective Synthesis of 4-Vinyl-2-oxazolidinones

DOI: 10.1016/0040-4039(91)80169-7

Source and publish data:

Tetrahedron Letters p. 6359 - 6362 (1991)

Update date:2022-07-29

Topics:

Authors:

Kimura, Masanari

Fugami, Keigo

Tanaka, Shuji

Tamaru, Yoshinao

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Article abstract of DOI:10.1016/0040-4039(91)80169-7

Silver(I) salts catalyze an amino cyclization of O-(2,3-butadienyl) N-tosyl-carbamates to provide mixtures of cis and trans-5-substituted N-tosyl-4-vinyl-2-oxazolidinones, the trans-isomers predominantly or exclusively.

Full text of DOI:10.1016/0040-4039(91)80169-7

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Product name:trans-N-acetyl-5-ethyl-4-vinyl-2-oxazolidinone

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