Tetrahedron p. 7887 - 7896 (1991)
Update date:2022-08-05
Topics:
Aquino, Mario
Cardani, Silvia
Fronza, Giovanni
Fuganti, Claudio
Fernandez, Rosalino Pulido
Tagliani, Auro
γ- and δ-Lactones 5, 6, 13, 14, 15 and 16 were synthesized via baker's yeast reduction of the corresponding keto acids 3, 4 and 9-12. The enantioselectivity of the reduction is strongly dependent on the nature of the keto acid; the δ-lactones ware always obtained in an ee% higher than the γ-lactones and ranging from 70% to 100%.
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