Enantiospecific total synthesis of (-)-allosamizoline, and aminocyclitol moiety of the insect chitinase inhibitor allosamidin

DOI: 10.1016/S0040-4039(00)92386-4

Source and publish data:

Tetrahedron Letters p. 5363 - 5366 (1991)

Update date:2022-08-04

Topics:

Authors:

Nakata, Masaya

Akazawa, Seiji

Kitamura, Shuji

Tatsuta, Kuniaki

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Article abstract of DOI:10.1016/S0040-4039(00)92386-4

Total synthesis of (-)-allosamizoline (2), an aminocyclitol moiety of the insect chitinase inhibitor allosamidin (1) has been enantiospecifically synthesized from D-glucosamine by using an intramolecular cycloaddition of the nitrile oxide to an olefin as a key step.

Full text of DOI:10.1016/S0040-4039(00)92386-4

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