Tetrahedron Letters p. 5363 - 5366 (1991)
Update date:2022-08-04
Topics:
Nakata, Masaya
Akazawa, Seiji
Kitamura, Shuji
Tatsuta, Kuniaki
Total synthesis of (-)-allosamizoline (2), an aminocyclitol moiety of the insect chitinase inhibitor allosamidin (1) has been enantiospecifically synthesized from D-glucosamine by using an intramolecular cycloaddition of the nitrile oxide to an olefin as a key step.
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Doi:10.1007/BF00755702
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