Journal of the Chemical Society, Dalton Transactions p. 2917 - 2920 (1991)
Update date:2022-08-03
Topics:
Ramesh, Krishnamoorthi
Bhuniya, Debnath
Mukherjee, Rabindranath
Complexes of high-spin manganese(III) (μeff = 4.79-5.30 at 298 K) with a closely related group of sexidentate Schiff-base ligands have been prepared and their solution properties thoroughly investigated.The brown to green crystalline complexes display ligand-to-metal charge-transfer transitions in the range 330-400 nm in addition to a crystal-field transition in the range 560-600 nm.The solution stereochemistry has been determined by paramagnetically shifted 1H NMR spectroscopy.Unlike the C3 symmetry in the solid-state structure, in solution the MnIIIN3O3 co-ordination sphere is severely distorted (ca.C1 symmetry).Cyclic voltammetric studies in dimethylformamide solution reveal an irreversible MnIII-MnII couple a quasi-reversible MnIV-MnIII couple (Ef in the range +0.42 to +0.86 V vs.SCE).
Zhejiang Kaili Industrial Co., Ltd
Contact:+86-571-85241926
Address:lantian business center,No.18 Moganshan Road
Contact:+86-570-4336358
Address:No.87 Building,Tianqian,Sidu Town
LinHai Cina Chemical Co., LTD.
Contact:0576-85580989
Address:Pharma-chem zone,Duqiao,Linhai,Zhejiang,China
Contact:+91 - 22 - 26355700
Address:17, Lotus Business Park, Andheri West
Zhuhai Rundu Pharmaceutical co.,Ltd
Contact:+86-756-7630755
Address:No.6,North Airport Road,Sanzao Town,Jinwan District
Doi:10.1007/s00706-011-0699-8
(2012)Doi:10.1021/jo970741r
(1997)Doi:10.1016/0223-5234(91)90125-7
(1991)Doi:10.1080/10426509908031613
(1999)Doi:10.1021/jm00317a045
(1967)Doi:10.1021/ja01264a054
(1942)
