Journal of the Chemical Society. Chemical communications p. 1597 - 1598 (1991)
Update date:2022-08-04
Topics:
Chai, Christina L. L.
Humphreys, Vanessa
Prout, Keith
Lowe, Gordon
A single diastereoisomer of phenyl epiandrosterone sulphite and the single diastereoisomer of benzyl epiandrosterone sulphite derived from it by nucleophilic substitution with benzyl alcohol have both been shown by X-ray crystallographic analysis to have the Rs configuration and hence the reaction proceeds with inversion at sulphur.
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