BF3·OEt2 promotes fast, mild, clean and regioselective dehydration of tertiary alcohols

DOI: 10.1016/0040-4039(91)80200-P

Source and publish data:

Tetrahedron Letters p. 6489 - 6492 (1991)

Update date:2022-07-30

Topics: Dehydration Regioselective Fast Mild Tertiary alcohols

Authors:

Posner Posner

Shulman-Roskes

Carry Carry

Green Green

Clark Clark

Dai Dai

Anjeh Anjeh

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80200-P

BF₃·OEt₂ in methylene chloride at 25°C for 2 hours or less is shown to be effective for easy conversion of tertiary alcohols into the corresponding thermodynamically most stable alkenes.

Full text of DOI:10.1016/0040-4039(91)80200-P

Products guided by the article

Product name:Benzene, [4-(1-methylethyl)-3-cyclohexen-1-yl]-

Cas No:138624-04-1

R&D Labs maybe for 138624-04-1

Shandong Topscience Biotech Co., Ltd.

Contact:0633-2619278

Address:No. 98 Lanshan West Road, Lanshan District, Rizhao, Shandong Province, P.R. of China
Anhui Redstar Pharmaceutical Corp., Ltd

Contact:+86-563-5120837

Address:Jingxian Industrial Development Zone, Anhui , China
Nanjing Habo Medical Technology Co., Ltd.

Contact:025－85769882

Address:No.108. Ganjiabian east. Qixia District .Nanjing
Taixing Joxin Bio-tec Co.,Ltd.

website:http://www.joxbio.com

Contact:86-523-87558858 87612088

Address:No.88, chengdong industrial park
Lonzeal Pharmaceuticals Co., Ltd.

website:http://www.lonzeal.com

Contact:+86-13381011962

Address:RM 801, Yue MOMA, No. 26 Anningzhuang Rd. Haidian District, Beijing, China

Relevant to this article

Lewis acid catalyzed synthesis of 1-aryl-1,2-dihydro-naphtho[1,2-e][1,3] oxazin-3-ones under solvent free conditions: A mechanistic approach

Doi:10.1002/jhet.825
(2012)
A poly(hydroxyethyl methacrylate)-immobilized chiral manganese(III)salen catalyst for asymmetric epoxidation of α-methylstyrene

Doi:10.1016/S1872-2067(11)60345-8
(2012)
Doi:10.1021/ja01878a081
(1939)
Reactions of 6-(tri- and 6-(difluoromethyl))comanic acids and their ethyl esters with aniline and its 2-substituted derivatives

Doi:10.1016/j.jfluchem.2012.06.003
(2012)
Enantioselective gold-catalyzed synthesis of polycyclic indolines

Doi:10.1021/ol300297t
(2012)
In silico design, synthesis and evaluation of 3′-O-benzylated analogs of salacinol, a potent α-glucosidase inhibitor isolated from an Ayurvedic traditional medicine salacia

Doi:10.1039/c2cc34144a
(2012)

Article Doi