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Syntheses and equilibria of fused bicyclic methylenecyclopropanes

DOI: 10.1039/C39740000383

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 383 - 384 (1974)

Update date:2022-08-03

Topics:

Authors:

Kende, Andrew S.Kende, Andrew S.

Riecke, Edgar E.Riecke, Edgar E.

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Article abstract of DOI:10.1039/C39740000383

Isomeric bicyclic methylenecyclopropanes, obtained from carbenoid ring contraction of bicyclic cyclobutanones, exhibit extraordinarily clean thermal equilibria which is entropy-controlled near the boundaries of Bredt's rule.

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