Tetrahedron Letters p. 6797 - 6800 (1991)
Update date:2022-08-05
Topics:
Lewis, Dorian P.
Muller, Philippe M.
Whitby, Richard J.
Jones, Raymond V. H.
The zirconium catalysed addition of diethylmagnesium to a variety of unactivated alkenes affords either the simple carbometallation product, or 1,4-dimagnesium reagents depending on the conditions and substrate.The products can be successfully functionalised with a variety of electrophiles.Key Words: Zirconium; Grignard; Carbometallation; 1,4-Dimagnesium; Catalysis.
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